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Unlockable: Aizen Sousuke
You must finish Arcade Mode with Ulquiorra.
Unlockable: Arturo Plateado
To unlock Arturo Plateado, beat Shihouin Yoruichi in episode mode.
Unlockable: Characters
- Aizen Sousuke - Clear Arcade Mode with Ulquiorra
- Arturo Plateado - Clear Episode Mode with Arturo Plateado
- Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
- Hinamori Momo - Clear Histugaya Toushiro's Story
- Hisago Shuuhei - Clear Episode Mode with Yamada Hanatarou
- Ichimaru Gin - Clear Arcade Mode with both Matsumoto Rangiku and Kira Izuru
- Kuchiki Rukia - Clear Abarai Renji's Story
- Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
- Kusajishi Yachiru - Clear Arcade Mode with both Yumichika Ayasegawa and Zaraki Kenpachi
- Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
- Madarame Ikkaku - Clear Episode Mode with Zaraki Kenpachi
- Shihouin Yoruichi - Clear Training Mode
- Soi Fon - Clear Episode Mode with Shihouin Yoruichi
- Tousen Kaname - Clear Arcade Mode with both Hisagi Shuuhei and Komamura Sajin
- Ulquiorra - Clear Arcade Mode with both Tousen Kaname and Ichimaru Gin
- Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
- Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
- Yamada Hanatarou - Clear Toushiro Hitsugaya's Story
- Yamamoto Genryuusai Shigenkuni - Clear Arcade Mode with Ukitake Juushiro
- Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku
Unlockable: Gin Ichimaru
To unlock Gin Ichimaru, complete Arcade Mode with Izuru and Ranginku.
Unlockable: Kisuke
To get Kisuke, defeat Mayrui in arcade mode.
Unlockable: Mayuri Kurosuchi
To unlock Mayuri Kurotsuchi for your use, defeat Uryu Ishida in Arcade Mode.
Unlockable: Old Man Yama
To unlock Old Man Yama as a playable character, you must beat Arcade Mode with Rukias Capton.
Unlockable: Treasure Box
To complete the game's art gallery, simply unlock all of the characters. After you do so, the Treasure Box will appear in the shop. The art gallery will be filled up thereafter, primarily with character drawings and other images.
Unlockable: Ulquiorra
To unlock Ulquiorra, complete Arcade Mode with Ichimaru Gin.
Unlockable: Uniforms
To unlock most alternate uniforms/outfits in the game, you must first unlock the character in question and then win fifteen battles in Versus Mode as that character.
Unlockable: Yoruchi
To play as Yoruchi, simply complete Tutorial Mode.
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